Loss of germination with age must be a somewhat complex process. That rehydration with water containing salts such as nitrate ion sometimes works when plain water (tap water or de-ionized?) doesn't implies (to me, anyway

an enzyme getting turned on or off rather than simple dehydration.
I store my seeds very dry (with Drierite, which gets them much drier than you can get with activated silica gel). They don't require a pre-soak for germination, so dehydration in and of itself doesn't preclude rapid germination. Certainly a lot of protein denaturation is going on as seeds age.
An interesting subject!