There was a pepper that was tested a few months ago at Warwick University that topped 1.4million, if I remember correctly. However, it is similar to the infinty in that it is not stable.
To be considered for the Guiness record holder, it needs to meet specific criteria. One could theoretically make a Jalapeno hotter than anything else by unstable crosses and stressing the plants.
But,it's a step in the right direction to a new way to damage yourself.
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